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101.
1 IntroductionThe Wupata'erkan Group, also called Wupata'erkanFormation (Wang et al., 1990), in the western SouthTianshan, China (Fig. 1), mainly comprises gray and darkgray fine-grained clastic rocks, interlayered with medium-acidic volcanic rocks (andesite and quartz porphyry),carbonates, cherts and variegated tuffaceousconglomerates. The chert in the formation was firstly foundin our field trip along sections of the Qiqi'erjianakesu Riverand Kekebiele Daban. Deformation of the group is…  相似文献   
102.
Abstract. Scanning electron microscopy-cathodoluminescence (SEM-CL) imaging of vein quartz in the Cu-mineralised, Shuteen Complex (South Gobi, Mongolia) has revealed a complex history of crystal growth, dissolution and microfracture healing, associated with several hydrothermal events that could not be detected using other observational techniques (e.g. transmitted/reflected light microscopy, back-scattered electron imaging, or secondary electron imaging).
The quartz initially grew as CL-bright/grey crystals in a 345±30C liquid reservoir, as inferred by the analysis of primary liquid fluid inclusions (average Th of 343C; 6.6∼7.7 wt% NaCleq). Quartz precipitation occurred at the edge of the crystals as reservoir fluids cooled to 260±25C, as indicated by micron-scale CL-dark/CL-bright quartz growth bands containing abundant fluid inclusions (with an average Th values of 261C). Pressure fluctuations were the likely cause of dissolution, as SEM-CL imaging reveals the quartz have corroded or rounded crystal edges, and precipitation of later quartz into open space. SEM-CL imaging shows the quartz contains healed microfractures that trapped low salinity fluids (3.9 wt% NaC1eq) with Th values of 173±15C.
SEM-CL imaging provides a means of deciphering the thermal and chemical evolution of the fossil Shuteen hydrothermal system, and the nature of hydrothermal quartz vein-forming processes, by facilitating the correlation of distinct fluid inclusion populations and their relative chronology, with specific hydrothermal events.  相似文献   
103.
The rift history of the Salta basin is related to the evolution of the Central Andes and to the activity of the Pacific margin, owing to its geographic location. Sedimentation occurred from the Neocomian to the Paleogene, with deposits reaching up to 5,000 m in thickness. Paleoenvironmental analysis reveals an evolutionary history controlled by tectonic and climatic changes. Isolated grabens characterized the early synrift stage; differential subsidence provoked distinct environments in the southern and northern subbasins. In the southern subbasins, alluvial-fan, fluvial-fan and lacustrine deposits prevail, whilst in the northern subbasins eolian and fluvial environments dominate. During the Maastrichtian, two major factors controlled the basin fill: the decrease in tectonic subsidence and a relative sea-level rise as recorded in South America. An extensive and shallow Atlantic marine ingression installed a carbonate system coincident with mainly humid conditions until the Danian. Until the Middle Eocene, the fluvial and lacustrine environmental evolution of the sag basin was controlled especially by the alternation of temperate with dry and humid periods. Paleontological records reflect these climatic changes and show their relationship to the sedimentation regime.  相似文献   
104.
Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.  相似文献   
105.
The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).  相似文献   
106.
The Merensky Reef and the underlying Upper Group 2 chromitite layer, in the Critical Zone of the Bushveld Complex, host much of the world’s platinum-group element (PGE) mineralization. The genesis is still debated. A number of features of the Merensky Reef are not consistent with the hypotheses involving mixing of magmas. Uniform mixing between two magmas over an area of 150 by 300 km and a thickness of 3–30 km seems implausible. The Merensky Reef occurs at the interval where Main Zone magma is added, but the relative proportions of the PGE in the Merensky Reef are comparable to those of the Critical Zone magma. Mineral and isotopic evidence in certain profiles through the Merensky Unit suggest either mixing of minerals, not magmas, and in one case, the lack of any chemical evidence for the presence of the second magma. The absence of cumulus sulphides immediately above the Merensky Reef is not predicted by this model. An alternative model is proposed here that depends upon pressure changes, not chemical processes, to produce the mineralization in chromite-rich and sulphide-rich reefs. Magma was added at these levels, but did not mix. This addition caused a temporary increase in the pressure in the extant Critical Zone magma. Immiscible sulphide liquid and/or chromite formed. Sinking sulphide liquid and/or chromite scavenged PGE (as clusters, nanoparticles or platinum-group minerals) from the magma and accumulated at the floor. Rupturing of the roof resulted in a pressure decrease and a return to sulphur-undersaturation of the magma.  相似文献   
107.
The Wupata‘erkan Group, also called Wupata‘erkan Formation, distributed in the South Tianshan, Xinjiang,China, mainly consists of gray and dark gray fine-grained clastic rocks, interlayered with volcanic rocks, carbonates and cherts. Some ultra-basic rocks (blocks) punctuate the formation. The formation was variously assigned to Silurian-Middle Devonian, Silurian-Lower Devonian, and pre-Devonian, mainly based on Atrypa bodini Mansuy, Hypothyridina parallelepipedia (Brour.) and Prismatophyllum hexagonum Yoh collected from the limestone interlayers, respectively.However, radiolarian fossils obtained from 24 chert specimens of the Wupata‘erkan Group, mainly include Albaillella sp.cf. A. undulata Deflandre, Albaillella sp. cf. A. paradoxa Deflandre, Albaillella cf. A. deflandrei Gourmelon, Albaillella sp. cf. A. indensis Won, Albaillella sp. cf. A. excelsa Ishiga, Kito and Imoto, Albaillella sp. and Latentifistulidae gen. et. sp.indet., are earliest Carboniferous and Late Permian. The earliest Carboniferous assemblage is characterized by Albaillella sp. cf. A. undulata Deflandre, Albaillella sp. cf. A. paradoxa Deflandre, Albaillella cf. A. deflandrei Gourmelon and Albaillella sp. cf. A. indensis Won, and the Late Permian assemblage by Albaillella sp. cf. A. excelsa Ishiga, Kito and Imoto. This new stratigraphic evidence indicates that the Wupata‘erkan Group is possibly composed of rocks with different ages from Silurian to Permian, and therefore, it is probably an ophiolite mrlange. The discovery of Late Permian Albaillella sp. cf. A. excelsa provides more reliable evidence supporting the existence of a Permian relic ancient oceanic basin in the western part of Xinjiang South Tianshan.  相似文献   
108.
Low‐pressure and high‐temperature (LP–HT) metamorphism of basaltic rocks, which occurs globally and throughout geological time, is rarely constrained by forward phase equilibrium modelling, yet such calculations provide valuable supplementary thermometric information and constraints on anatexis that are not possible to obtain from conventional thermometry. Metabasalts along the southern margin of the Sudbury Igneous Complex (SIC) record evidence of high‐grade contact metamorphism involving partial melting and melt segregation. Peak metamorphic temperatures reached at least ~925°C at ~1–3 kbar near the SIC contact. Preservation of the peak mineral assemblage indicates that most of the generated melt escaped from these rocks leaving a residuum characterized by a plagioclase–orthopyroxene–clinopyroxene–ilmenite‐magnetite±melt assemblage. Peak temperatures reached ~875°C up to 500 m from the SIC lower contact, which marks the transition to metabasalts that only experienced incipient partial melting without melt loss. Metabasalts ~500 to 750 m from the SIC contact are characterized by a similar two‐pyroxene mineral assemblage, but typically contain abundant hornblende that overgrew clino‐ and orthopyroxene along an isobaric cooling path. Metabasalts ~750 to 1,000 m from the SIC contact are characterized by a hornblende–plagioclase–quartz–ilmenite assemblage indicating temperatures up to ~680°C. Mass balance and phase equilibria calculations indicate that anatexis resulted in 10–20% melt generation in the inner ~500 m of the aureole, with even higher degrees of melting towards the contact. Comparison of multiple models, experiments, and natural samples indicates that modelling in the Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCFMASHTO) system results in the most reliable predictions for the temperature of the solidus. Incorporation of K2O in the most recent amphibole solution model now successfully predicts dehydration melting by the coexistence of high‐Ca amphibole and silicate melt at relatively low pressures (~1.5 kbar). However, inclusion of K2O as a system component results in prediction of the solidus at too low a temperature. Although there are discrepancies between modelling predictions and experimental results, this study demonstrates that the pseudosection approach to mafic rocks is an invaluable tool to constrain metamorphic processes at LP–HT conditions.  相似文献   
109.
New pseudosection modelling was applied to better constrain the P–T conditions and evolution of glaucophane‐bearing rocks in the Tamayen block of the Yuli belt, recognized as the world's youngest known blueschist complex. Based on the predominant clinoamphibole, textural relationships, and mineral compositions, these glaucophane‐bearing high‐P rocks can be divided into four types. We focused on the three containing garnet. The chief phase assemblages are (in decreasing mode): amphibole + quartz + epidote + garnet + chlorite + rutile/titanite (Type‐I), phengite + amphibole + quartz + garnet + chlorite + epidote + titanite + biotite + magnetite (Type‐II), and amphibole + quartz + albite + epidote + garnet + rutile + hematite + titanite (Type‐III). Amphibole exhibits compositional zoning from core to rim as follows: glaucophane → pargasitic amphibole → actinolite (Type‐I), barroisite → Mg‐katophorite/taramite → Fe‐glaucophane (Type‐II), glaucophane → winchite (Type‐III). Using petrographic data, mineral compositions and Perple_X modelling (pseudosections and superimposed isopleths), peak P–T conditions were determined as 13 ± 1 kbar and 550 ± 40 °C for Type‐I, 10.5 ± 0.5 kbar and 560 ± 30 °C for Type‐II (thermal peak) and 11 ± 1 kbar and 530 ± 30 °C for Type‐III. The calculations yield higher pressures and temperatures than previously thought; the difference is ~1–6 kbar and 50–200 °C. The three rock types record similar P–T retrograde paths with clockwise trajectories; all rocks followed trajectories with substantial pressure decrease under near‐isothermal conditions (Type‐I and Type‐III), with the probable exception of Type‐II where decompression followed colder geotherms. The P–T paths suggest a tectonic environment in which the rocks were exhumed from maximum depths of ~45 km within a subduction channel along a relative cold geothermal gradient of ~11–14 °C km?1.  相似文献   
110.
The numerical age of the Albian/Cenomanian (A/C) boundary (=Early/Late Cretaceous Epoch boundary) has recently been updated using new radiometric dates from Hokkaido, Japan. Yet, an element of uncertainty still remains in the age scaling due to inaccurate chronostratigraphic contexts surrounding the tuff beds that have been geochronologically studied in the Oyubari and Soeushinai areas. To ensure stability in the Cretaceous time scale, this paper rigorously reevaluates the current status of Hokkaido A/C chronology, clarifying the limitations and making refinements via proper reintegration of published chronostratigraphic data. In the case of the Oyubari area, its A/C biostratigraphic scheme is limited by near-absence of ammonites and planktonic foraminifera at the Albian–Cenomanian transition, resulting in a large discrepancy in the proposed boundary levels based on these macro- and microfossil taxa. These problems can be solved by solid data integration aided by event- and δ13C-sratigraphy from the adjacent Ashibetsu area, wherein the A/C boundary is well documented by the superior planktonic foraminiferal record. Based on the resultant A/C boundary redefinition for the Oyubari area in conjunction with a simple linear interpolation from two published UPb ages, the A/C boundary age can be independently calibrated to be 100.8 Ma [with ±1.4 Myr uncertainty (=analytical precision)], which is consistent with that currently in use in the Geologic Time Scale 2012 (100.5 ± 0.4 Ma). In the case of the Soeushinai area, its chronostratigraphic framework is limited by rather complex geological structure and vertically/laterally variable lithologies. Moreover, the accuracy of geochronological data from this area is undermined by the fact that the dated tuff levels do not bracket the inferred A/C boundary.  相似文献   
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